Issue 21, 2007
From the journal:

Chemical Communications

Synthesis and structural characterization of lanthanide complexes with the di- or tri-anionic diguanidinate ligand: new insight into the flexibility and distinct reactivity of the linked diguanidinate ligand†

Chengfu Pi,a   Zhenyu Zhu,a   Linhong Weng,a   Zhenxia Chena  and  Xigeng Zhou*ab  

* Corresponding authors

a Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, Shanghai, People's Republic of China
E-mail: xgzhou@fudan.edu.cn
Fax: +86 21 65643769
Tel: +86 21 65641740

b State Key Laboratory of Organometallic Chemistry, Shanghai, People's Republic of China

Abstract

Unprecedented disproportionation and deprotonation of the linked diguanidinate ligand have been established, demonstrating, for the first time, that the number and distribution of negative charges on the diguanidinate ligand are tunable, and representing a new and efficient method for synthesis of linked diguanidinate di- and tri-anion complexes.

Graphical abstract: Synthesis and structural characterization of lanthanide complexes with the di- or tri-anionic diguanidinate ligand: new insight into the flexibility and distinct reactivity of the linked diguanidinate ligand

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Article information

DOI
https://doi.org/10.1039/B618151A
Article type
Communication
Submitted
13 Dec 2006
Accepted
09 Feb 2007
First published
05 Mar 2007

Chem. Commun., 2007, 2190-2192

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Synthesis and structural characterization of lanthanide complexes with the di- or tri-anionic diguanidinate ligand: new insight into the flexibility and distinct reactivity of the linked diguanidinate ligand

C. Pi, Z. Zhu, L. Weng, Z. Chen and X. Zhou, Chem. Commun., 2007, 2190 DOI: 10.1039/B618151A

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