New evidence supporting the hypothesis that the biosynthesis of the N-N bond of the antibiotic valanimycin involves the reaction of a hydroxylamine with an amine to give a hydrazine is obtained by partial purification of a hydroxylamine-forming enzyme and by successful incorporation experiments with a postulated hydrazine intermediate.
R. J. Parry and W. Li, J. Chem. Soc., Chem. Commun., 1994, 995 DOI: 10.1039/C39940000995
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