Issue 45, 2024

Tuning the pore chemistry of Zr-MOFs for efficient metal ion capture from complex streams

Abstract

Metal–organic frameworks (MOFs) have shown promise for adsorptive separations of metal ions. Herein, MOFs based on highly stable Zr(IV) building units were systematically functionalized with targeted metal binding groups. Through competitive adsorption studies, it was shown that the selectivity for different metal ions was directly tunable through functional group chemistry.

Graphical abstract: Tuning the pore chemistry of Zr-MOFs for efficient metal ion capture from complex streams

Supplementary files

Article information

Article type
Communication
Submitted
22 Jan 2024
Accepted
27 Apr 2024
First published
29 Apr 2024

Chem. Commun., 2024,60, 5808-5811

Tuning the pore chemistry of Zr-MOFs for efficient metal ion capture from complex streams

R. E. Sikma, B. Song, J. I. Deneff, J. Smith, K. Sanchez, R. A. Reyes, L. M. Lucero, K. J. Fritzsching, A. G. Ilgen and D. F. Sava Gallis, Chem. Commun., 2024, 60, 5808 DOI: 10.1039/D4CC00320A

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