Issue 17, 2006
From the journal:

Chemical Communications

A tris-pyrazolylborateligand with hemilabile O-donor groups. Examples of η3, η5, η6 and bridging modes of bonding to Li+, Na+, K+, Tl+ and Ca2+ ions†

Malcolm H. Chisholm,*a   Judith C. Galluccia  and  Gülşah Yamana  

* Corresponding authors

a Newman and Wolfrom Laboratories, The Ohio State University, 100 W. 18th Avenue, Columbus, USA
E-mail: chisholm@chemistry.ohio-state.edu
Fax: +1-614-292 0368
Tel: +1-614-292 7216

Abstract

A tris-pyrazolylborate ligand bearing ether appendages is shown to be a potential hemilabile ligand based on NMR studies and structural characterization of its η3, η5, η6, and μ-binding modes in coordination with Li+, Na+, K+, Tl+, and Ca2+ ions.

Graphical abstract: A tris-pyrazolylborate ligand with hemilabile O-donor groups. Examples of η3, η5, η6 and bridging modes of bonding to Li+, Na+, K+, Tl+ and Ca2+ ions

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Article information

DOI
https://doi.org/10.1039/B517640A
Article type
Communication
Submitted
14 Dec 2005
Accepted
21 Feb 2006
First published
21 Mar 2006

Chem. Commun., 2006, 1872-1874

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A tris-pyrazolylborate ligand with hemilabile O-donor groups. Examples of η3, η5, η6 and bridging modes of bonding to Li+, Na+, K+, Tl+ and Ca2+ ions

M. H. Chisholm, J. C. Gallucci and G. Yaman, Chem. Commun., 2006, 1872 DOI: 10.1039/B517640A

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