Issue 24, 2010
From the journal:

Chemical Communications

Ammonia N–H activation by a N,N′-diamidocarbene†

Todd W. Hudnall,a   Jonathan P. Moerdyka  and  Christopher W. Bielawski*a  

* Corresponding authors

a Department of Chemistry and Biochemistry, The University of Texas at Austin, 1 University Station A5300, Austin, USA
E-mail: bielawski@cm.utexas.edu

Abstract

The synthesis and characterization of N,N′-dimesityl-4,6-diketo-5,5-dimethylpyrimidin-2-ylidene is reported; this crystalline N,N′-diamidocarbene was found to split ammonia and engage in other reactions not exhibited by typical N-heterocyclic carbenes.

Graphical abstract: Ammonia N–H activation by a N,N′-diamidocarbene

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Article information

DOI
https://doi.org/10.1039/C0CC00638F
Article type
Communication
Submitted
29 Mar 2010
Accepted
16 Apr 2010
First published
18 May 2010

Chem. Commun., 2010,46, 4288-4290

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Ammonia N–H activation by a N,N′-diamidocarbene

T. W. Hudnall, J. P. Moerdyk and C. W. Bielawski, Chem. Commun., 2010, 46, 4288 DOI: 10.1039/C0CC00638F

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