The X-ray crystal structure of {P(S)[N(CH3)NH2]3} reveals a tubular architecture arising out of the N–H⋯S![[double bond, length as m-dash]](https://www.rsc.org/images/entities/char_e001.gif)
P hydrogen bonds while the corresponding structure of {P(O)[N(CH3)NH2]3} shows a 2-D organization mediated by the N–H⋯OP hydrogen bonds.
![Graphical abstract: A tubular architecture in a phosphorus based trihydrazide, {P(S)[N(CH3)NH2]3}](/en/Image/Get?imageInfo.ImageType=GA&imageInfo.ImageIdentifier.ManuscriptID=B504753F&imageInfo.ImageIdentifier.Year=2005)
V. Chandrasekhar and R. Azhakar, CrystEngComm, 2005, 7, 346 DOI: 10.1039/B504753F
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