Issue 1, 2005
From the journal:

Chemical Communications

From atactic to isotactic CO/p-methylstyrenecopolymer by proper modification of Pd(ii) catalysts bearing achiral α-diimines†

Barbara Binotti,a   Carla Carfagna,*a   Cristiano Zuccacciab  and  Alceo Macchioni*b  

* Corresponding authors

a Istituto di Scienze Chimiche, Università di Urbino, Piazza Rinascimento, Urbino, Italy
E-mail: schim@uniurb.it
Fax: 00390722303311
Tel: 00390722303312

b Dipartimento di Chimica, Università di Perugia, via Elce di Sotto, Perugia, Italy
E-mail: alceo@unipg.it
Fax: 00390755855598
Tel: 00390755855579

Abstract

Cationic Pd(II) complexes modified with achiral C2v-symmetric α-diimine ligands allow preparation of atactic or isotactic stereoblock CO/p-methylstyrene copolymers; both catalyst activity and polyketone microstructure depend on the choice of α-diimine substituents and counterion.

Graphical abstract: From atactic to isotactic CO/p-methylstyrene copolymer by proper modification of Pd(ii) catalysts bearing achiral α-diimines

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Article information

DOI
https://doi.org/10.1039/B411214H
Article type
Communication
Submitted
22 Jul 2004
Accepted
10 Nov 2004
First published
29 Nov 2004

Chem. Commun., 2005, 92-94

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From atactic to isotactic CO/p-methylstyrene copolymer by proper modification of Pd(II) catalysts bearing achiral α-diimines

B. Binotti, C. Carfagna, C. Zuccaccia and A. Macchioni, Chem. Commun., 2005, 92 DOI: 10.1039/B411214H

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