Issue 23, 2004
From the journal:

Chemical Communications

Aqueous hydrogenation of carbon dioxide catalysed by water-soluble ruthenium aqua complexes under acidic conditions

Hideki Hayashi,a   Seiji Ogo*a  and  Shunichi Fukuzumi*a  

* Corresponding authors

a Department of Material and Life Science, Graduate School of Engineering, Osaka University, PRESTO & CREST, Japan Science and Technology Agency (JST), Suita, Japan
E-mail: ogo@ap.chem.eng.osaka-u.ac.jp
Fax: +81 6 6879 7370
Tel: +81 6 6879 4140

Abstract

Hydrogenation of carbon dioxide (P(H2/CO2) = 5.5/2.5 MPa) into formic acid (HCOOH) under acidic conditions (pH 2.5–5.0) in water has been achieved by using water-soluble ruthenium aqua catalysts [(η6-C6Me6)RuII(L)(OH2)]SO4 (L = 2,2′-bipyridine or 4,4′-dimethoxy-2,2′-bipyridine).

Graphical abstract: Aqueous hydrogenation of carbon dioxide catalysed by water-soluble ruthenium aqua complexes under acidic conditions

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B411633J
Article type
Communication
Submitted
29 Jul 2004
Accepted
08 Sep 2004
First published
14 Oct 2004

Chem. Commun., 2004, 2714-2715

Permissions

Request permissions

Aqueous hydrogenation of carbon dioxide catalysed by water-soluble ruthenium aqua complexes under acidic conditions

H. Hayashi, S. Ogo and S. Fukuzumi, Chem. Commun., 2004, 2714 DOI: 10.1039/B411633J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements