Issue 1, 2003
From the journal:

Green Chemistry

Conversion of the hydroxyl group in 1-hexyl alcohol to an amide group in supercritical water without catalyst

Mitsuru Sasaki,*a   Junko Nishiyama,b   Munehiro Uchida,b   Kohtaro Goto,c   Kiyohiko Tajima,c   Tadafumi Adschirib  and  Kunio Arai*b  

* Corresponding authors

a Genesis Research Institute, Inc, 4-1-35 Noritake-shinmachi, Nishi-ku, Nagoya, Japan
E-mail: sasaki@arai.che.tohoku.ac.jp
Fax: +81 22 217 7246
Tel: +81 22 217 7248

b Department of Chemical Engineering, Tohoku University, 7 Aza-Aoba, Aramaki, Aoba-ku, Sendai, Japan
E-mail: karai@arai.che.tohoku.ac.jp
Fax: +81 22 217 7246
Tel: +81 22 217 7245

c Noguchi Institute, 1-8-1 Kaga, Itabashi-ku, Tokyo, Japan

Abstract

The main reaction pathway in the reaction between 1-hexyl alcohol and acetamide in subcritical and supercritical water without catalyst is proposed and the optimum conditions where amidation of 1-hexyl alcohol can selectively occur are explored.

Graphical abstract: Conversion of the hydroxyl group in 1-hexyl alcohol to an amide group in supercritical water without catalyst

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Article information

DOI
https://doi.org/10.1039/B211451H
Article type
Paper
Submitted
22 Nov 2002
First published
27 Jan 2003

Green Chem., 2003,5, 95-97

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Conversion of the hydroxyl group in 1-hexyl alcohol to an amide group in supercritical water without catalyst

M. Sasaki, J. Nishiyama, M. Uchida, K. Goto, K. Tajima, T. Adschiri and K. Arai, Green Chem., 2003, 5, 95 DOI: 10.1039/B211451H

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