Issue 19, 2003
From the journal:

Chemical Communications

Redox-triggered on/off coordination of a bridgehead nitrogen donor in a tripodal iron complex

Stefan Wörl,a   Dieter Hellwinkel,b   Hans Pritzkowa  and  Roland Krämer*a  

* Corresponding authors

a Anorganisch-Chemisches Institut, Im Neuenheimer Feld 270, D-69120 Heidelberg, Germany
E-mail: Roland.Kraemer@urz.uni-heidelberg.de
Fax: 49 6221 548599
Tel: 49 6221 548438

b Organisch-Chemisches Institut, Universität Heidelberg, Im Neuenheimer Feld 270, D-69120 Heidelberg, Germany

Abstract

We report the unprecedented redox-triggered on/off coordination of a bridgehead nitrogen donor in an iron complex of the tripodal ligand 2,2′,2″-nitrilotribenzoate; the complex is an efficient redox catalyst for H2O2 oxidation of hydroquinone while complexes of related ligands are inactive.

Graphical abstract: Redox-triggered on/off coordination of a bridgehead nitrogen donor in a tripodal iron complex

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Article information

DOI
https://doi.org/10.1039/B307277K
Article type
Communication
Submitted
26 Jun 2003
Accepted
21 Aug 2003
First published
04 Sep 2003

Chem. Commun., 2003, 2506-2507

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Redox-triggered on/off coordination of a bridgehead nitrogen donor in a tripodal iron complex

S. Wörl, D. Hellwinkel, H. Pritzkow and R. Krämer, Chem. Commun., 2003, 2506 DOI: 10.1039/B307277K

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