Issue 43, 2023

Heterovalent tin ion-regulated bromobismuth double perovskite-based fully-inorganic solar cells

Abstract

Recently, lead-free halide double perovskites have evolved to be a promising photo-absorber for photovoltaic applications due to their high thermal and moisture stability and negligible toxicity. However, their photovoltaic performance is still limited owing to improper film quality, inappropriate band gap, and high defect density. Herein, we report Cs2AgBiBr6 double perovskite (DP)-based fully-inorganic solar cells with enhanced photovoltaic performance accomplished via heterovalent Sn2+ doping. The band gap of the DP photo-absorber is reduced by carefully controlling the Sn2+ doping concentration and subsequently its charge extraction capability is improved. In addition, Sn2+ incorporation has improved the surface morphology, carrier lifetime, defect states and electron mobility of the DP layer. Meanwhile, an upshift of the valence band maximum energy of Cs2AgBiBr6 (from −6.41 eV to −6.32 eV) with Sn2+ incorporation is observed via ultra-violet photoelectron spectroscopy (UPS) analysis. This re-alignment of energy levels between the perovskite absorber layer and the hole transport layer has created an efficient pathway for hole extraction and transport at the interface. As a result, the optimized Sn-doped device exhibits a remarkably enhanced photo conversion efficiency (PCE) of 2.74% with an excellent open-circuit voltage (Voc) of 1.02 V. The Sn-doped device also shows higher stability over the pristine device for several weeks in ambient atmosphere without encapsulation. This work demonstrates that doping Cs2AgBiBr6 photo-absorber with Sn2+ is an effective approach for efficiency enhancement in PSCs and paves new ways for high performance lead-free stable photovoltaic applications.

Graphical abstract: Heterovalent tin ion-regulated bromobismuth double perovskite-based fully-inorganic solar cells

Supplementary files

Article information

Article type
Paper
Submitted
02 Aug 2023
Accepted
15 Oct 2023
First published
16 Oct 2023

J. Mater. Chem. C, 2023,11, 15347-15356

Heterovalent tin ion-regulated bromobismuth double perovskite-based fully-inorganic solar cells

A. Dehingia, U. Das and A. Roy, J. Mater. Chem. C, 2023, 11, 15347 DOI: 10.1039/D3TC02750C

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