Issue 107, 2002
From the journal:

CrystEngComm

Alternating cationic–anionic layers in the [Mii(H2O)6][Cuii(mal)2(H2O)] complexes linked through hydrogen bonds (M = Mn, Co, Ni, Cu and Zn; H2mal = malonic acid)

Yolanda Rodríguez-Martín,a   Joaquín Sanchiz,b   Catalina Ruiz-Pérez,*a   Francesc Lloretc  and  Miguel Julve*c  

* Corresponding authors

a Laboratorio de Rayos X y Materiales Moleculares, Departamento de Física Fundamental II, Facultad de Física, Universidad de La Laguna, Avda. Astrofísico Francisco Sánchez s/n, 38204-La Laguna, Tenerife, Spain
E-mail: caruiz@ull.es

b Departamento de Química Inorgánica, Facultad de Farmacia, Universidad de La Laguna, Avda. Astrofísico Sánchez s/n, 38204 La Laguna, Tenerife, Spain

c Departamento de Química Inorgánica/Instituto de Ciencia Molecular, Facultad de Química, Universitat de València, Avda Dr. Moliner 50, Burjassot, Valencia, Spain

Abstract

The compounds of formula [MII(H2O)6][CuII(mal)2(H2O)2] [M = Mn (1), Co (2), Ni (3), Cu (4), Zn (5) and H2mal = malonic acid] have been prepared and structurally characterised. Each compound adopts a structure where the layers of [Cu(mal)2(H2O)2]2− anions alternate with layers of [M(H2O)6]2+ cations. The layers are linked to each other through hydrogen bonds affording a three-dimensional network. A quasi-Curie law behaviour is observed for the complexes 1–5 in the temperature range 2.0–298 K.

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Article information

DOI
https://doi.org/10.1039/B206728E
Article type
Paper
Submitted
15 Jul 2002
Accepted
21 Nov 2002
First published
11 Dec 2002

CrystEngComm, 2002,4, 631-637

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Alternating cationic–anionic layers in the [MII(H2O)6][CuII(mal)2(H2O)] complexes linked through hydrogen bonds (M = Mn, Co, Ni, Cu and Zn; H2mal = malonic acid)

Y. Rodríguez-Martín, J. Sanchiz, C. Ruiz-Pérez, F. Lloret and M. Julve, CrystEngComm, 2002, 4, 631 DOI: 10.1039/B206728E

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