Issue 35, 2002
From the journal:

CrystEngComm

Basket weave-like 2-D coordination polymer generated by the self-assembly of [Mn(H2O)6]2+ and geometrically anisotropic [W(CN)6bpy]2− precursors

Janusz Szklarzewicz,a   Robert Podgajny,a   Krzysztof Lewińskia  and  Barbara Sieklucka*a  

* Corresponding authors

a Faculty of Chemistry, Jagiellonian University, Ingardena 3, 30-060 Kraków, Poland
E-mail: siekluck@chemia.uj.edu.pl

Abstract

The architecture of 2-D [Mn(H2O)3][W(CN)6bpy]·4.5H2O is controlled by CN-bridging of [W(CN)6bpy]2− to [Mn(H2O)3]2+, face-to-face π-stacking interactions within pairs of [W(CN)6bpy]2− and an extensive network of hydrogen bonds; it provides the first example of a cyano-bridged bimetallic supramolecular assembly of 4.82 topology of a basket weave-like pattern.

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Article information

DOI
https://doi.org/10.1039/B203674F
Article type
Paper
Submitted
16 Apr 2002
Accepted
24 May 2002
First published
25 Jun 2002

CrystEngComm, 2002,4, 199-201

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Basket weave-like 2-D coordination polymer generated by the self-assembly of [Mn(H2O)6]2+ and geometrically anisotropic [W(CN)6bpy]2− precursors

J. Szklarzewicz, R. Podgajny, K. Lewiński and B. Sieklucka, CrystEngComm, 2002, 4, 199 DOI: 10.1039/B203674F

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