Issue 55, 2002

Supramolecular assembly of low-dimensional silver(i) architectures: testing the reliability of the self-complementary oxime⋯oxime hydrogen-bond interaction

Abstract

The syntheses and crystal structure determinations of three new compounds, bis-[4′-[N-(4-pyridylmethylene)]aminoacetophenone oxime] silver(I) hexafluorophosphate hydrate, bis-[4′-[N-(4-pyridylmethylene)]aminoacetophenone oxime] silver(I) perchlorate hydrate, and bis-[3′-[N-(4-pyridylmethylene)]aminoacetophenone oxime] silver(I) hexafluorophosphate hydrate, demonstrate that the desired primary supramolecular synthon, the oxime⋯oxime dimer, is not disrupted despite extensive ligand modifications (through covalent synthesis) that increase the aromatic content and introduce an additional hydrogen-bond acceptor moiety.

Article information

Article type
Paper
Submitted
05 Mar 2002
Accepted
13 May 2002
First published
17 Jul 2002

CrystEngComm, 2002,4, 310-314

Supramolecular assembly of low-dimensional silver(I) architectures: testing the reliability of the self-complementary oxime⋯oxime hydrogen-bond interaction

C. B. Aakeröy, A. M. Beatty and D. S. Leinen, CrystEngComm, 2002, 4, 310 DOI: 10.1039/B202303M

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