Issue 1, 2002
From the journal:

Chemical Communications

A novel multidecker sandwich complex from the reaction of ferrocene with GaCl3

Stefan Scholz,a   Jennifer C. Green,b   Hans-Wolfram Lerner,a   Michael Boltec  and  Matthias Wagner*a  

* Corresponding authors

a Institut für Anorganische Chemie, J. W. Goethe-Universität Frankfurt, Marie-Curie-Str. 11, Frankfurt (Main), Germany.
E-mail: Matthias.Wagner@chemie.uni-frankfurt.de

b Inorganic Chemistry Laboratory, South Parks Road, Oxford, UK

c Institut für Organische Chemie, J. W. Goethe-Universität Frankfurt, Marie-Curie-Str. 11, Frankfurt (Main), Germany

Abstract

A redox reaction takes place between GaCl3 and an excess of ferrocene, leading to the multidecker sandwich complex 1, [–Ga(C5H5)Fe(C5H5)Ga(C 5H5)Fe(C5H5)–]n[GaCl4]2n, which features an array of alternating Ga(I) and Fe(II) ions bridged by cyclopentadienyl moieties.

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Article information

DOI
https://doi.org/10.1039/B108515H
Article type
Communication
Submitted
20 Sep 2001
Accepted
21 Nov 2001
First published
13 Dec 2001

Chem. Commun., 2002, 36-37

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A novel multidecker sandwich complex from the reaction of ferrocene with GaCl3

S. Scholz, J. C. Green, H. Lerner, M. Bolte and M. Wagner, Chem. Commun., 2002, 36 DOI: 10.1039/B108515H

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