A designed material with large birefringence and remarkable deep-ultraviolet transparency, KF·B(OH)3, has been discovered. The well-aligned [F·B(OH)3]− layers endow a very large bandgap (7.63 eV), comparably large birefringence (0.114 @1064 nm), and the reinforced interlayer bonding of ca. 2.16 × KBe2BO3F2.
Y. Li, X. Chen and K. M. Ok, Chem. Commun., 2022, 58, 8770 DOI: 10.1039/D2CC03495F
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