Issue 4, 2001

Kinetic and stereospecific manifestations of a set of active centres in butadiene polymerization under the action of a catalytic system based on NdCl3·3TBP

Abstract

The unusual dependence of butadiene conversion and polymer microstructure on the ratio Mg/Nd or Al/Nd during the polymeriza-tion of butadiene under the action of NdCl3·3TBPAlBu3iMgBu(i-C8H17) can be explained by the formation of a set of active centres in the catalytic system.

Article information

Article type
Paper

Mendeleev Commun., 2001,11, 157-159

Kinetic and stereospecific manifestations of a set of active centres in butadiene polymerization under the action of a catalytic system based on NdCl3·3TBP

Y. B. Monakov, Z. M. Sabirov, N. V. Duvakina, V. N. Urazbaev and O. A. Ponomareva, Mendeleev Commun., 2001, 11, 157 DOI: 10.1070/MC2001v011n04ABEH001358

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