Aromatization of cyclic hydrocarbons via thioether elimination reaction

Yang Liu; Yingqi Feng; Jinli Nie; Sijie Xie; Xin Pen; Huanliang Hong; Xiuwen Chen; Lu Chen; Yibiao Li

doi:10.1039/D3CC03279E

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Aromatization of cyclic hydrocarbons via thioether elimination reaction†

Yang Liu,^a Yingqi Feng,^a Jinli Nie,^a Sijie Xie,^a Xin Pen,^a Huanliang Hong,

^a Xiuwen Chen,

^a Lu Chen^a and Yibiao Li

*^a

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* Corresponding authors

^a School of Biotechnology and Health Sciences, Wuyi University, Jiangmen, Guangdong Province 529090, China
E-mail: leeyib268@126.com

Abstract

Herein, the diversity-oriented aromatization of cyclic hydrocarbons via potassium ethyl xanthogenate (EtOCS₂K)/NH₄I-mediated methylthiyl radical addition and thioether elimination was investigated under transition-metal-free conditions. The methylthiyl radical species were generated in situ via the NH₄I-mediated decomposition of DMSO following which EtOCS₂K promoted the breaking of carbon–sulfur bonds of thioether.

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DOI: https://doi.org/10.1039/D3CC03279E
Article type: Communication
Submitted: 07 Jul 2023
Accepted: 24 Aug 2023
First published: 25 Aug 2023

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Chem. Commun., 2023,59, 11232-11235

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Aromatization of cyclic hydrocarbons via thioether elimination reaction

Y. Liu, Y. Feng, J. Nie, S. Xie, X. Pen, H. Hong, X. Chen, L. Chen and Y. Li, Chem. Commun., 2023, 59, 11232 DOI: 10.1039/D3CC03279E

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Chemical Communications

Aromatization of cyclic hydrocarbons via thioether elimination reaction†

Abstract

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Aromatization of cyclic hydrocarbons via thioether elimination reaction

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