The synthesis of unsymmetrical push–pull benzoporphyrins has been realized. UV-Vis and fluorescence spectroscopy, cyclic voltammetry and DFT calculations reveal subtle substituent effects on the electronic and optical properties of these porphyrins.
R. G. W. Jinadasa, Y. Fang, Y. Deng, R. Deshpande, X. Jiang, K. M. Kadish and H. Wang, RSC Adv., 2015, 5, 51489 DOI: 10.1039/C5RA09179A
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