The lowest-energy fragmentation pathway of trineopentylstannyl cation is the first example of β-methyl migration to an organotin compound in the gas-phase; the origin of the migrating methyl groups is confirmed by an isotopic labelling experiment.
D. Dakternieks, A. E. K. Lim and K. F. Lim, Chem. Commun., 1999, 1425 DOI: 10.1039/A903098K
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