Silylketenes bearing a range of substituents (alkyl, alkenyl, aryl, heteroaryl) are prepared by an unusual rhodium mediated Wolff rearrangement of the corresponding silyl diazo ketones.
S. P. Marsden and W. Pang, Chem. Commun., 1999, 1199 DOI: 10.1039/A902549I
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