The first free-base meso-tetraarylporphyrin coordination polymer is assembled from meso-tetrapyridylporphyrin and HgBr2via 4-connected peripheral ligation, and it possesses a novel one-dimensional structural motif with large interporphyrin cavities.
L. Pan, X. Wang and B. C. Noll, Chem. Commun., 1999, 157 DOI: 10.1039/A807242F
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