The molecular structure of gaseous 2-fluoro-3,5-di-tert-butyl-1,3,2-oxazaphospholene has been determined by electron diffraction and ab initio calculations. The structural analysis has shown that the diheterophospholene ring possesses a P-envelope conformation with axial orientation of the P-F bond which is very long, 1.641(11) °.
V. A. Naumov, M. Dakkuori, R. N. Ziatdinova and H. Oberhammer, Mendeleev Commun., 1998, 8, 89 DOI: 10.1070/MC1998v008n03ABEH000930
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