Octaalkoxy substituted PdII–η1-benzylideneaniline complexes with a more disc-like shape can give rise to a calamitic smectic phase and low melting transition temperatures comparable to those of the corresponding free ligands.
M. Lee, Y. Yoo, M. Choi and H. Chang, J. Mater. Chem., 1998, 8, 277 DOI: 10.1039/A708128F
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