Issue 9, 1998
From the journal:

Journal of Chemical Research, Synopses

Relative Ease of Formation of Alkylidine(oxo and thioxo)phosphorane Intermediates in Nucleophilic Substitution at Phosphonyl and Thiophosphonyl Centres

Caroline D. Cox  and  Martin J. P. Harger  

Abstract

The conversion of R2CHP(X)(NEt2)Cl (R2CH=9-fluorenyl) into R2CHP(X)(NEt2)2via the intermediate R2C[double bond, length as m-dash]P(X)NEt2 (elimination–addition mechanism) is much faster when X=S than when X=O.

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Article information

DOI
https://doi.org/10.1039/A802407C
Article type
Paper

J. Chem. Res. (S), 1998, 578-579

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Relative Ease of Formation of Alkylidine(oxo and thioxo)phosphorane Intermediates in Nucleophilic Substitution at Phosphonyl and Thiophosphonyl Centres

C. D. Cox and M. J. P. Harger, J. Chem. Res. (S), 1998, 578 DOI: 10.1039/A802407C

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