A concerted hydrogen-atom transfer one-electron transfer mechanism is proposed for the ruthenium(III)-catalysed oxidation of 2-methylpentane-2,4-diol by alkaline hexacyanoferrate(III).
A. E. Mucientes, F. J. Poblete, R. E. Gabaldon, M. A. Rodriguez and F. Santiago, J. Chem. Res. (S), 1998, 286 DOI: 10.1039/A708849C
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