Three stereogenic centers bearing azide, methoxy, and ethylthio groups, have been constructed stereoselectively using the sole chirality of the Fe(CO)3 group with concurrent 1,2-migration of the Fe(CO)3 group and the obtained product was converted to an anti-aminoalcohol derivative to determine the absolute stereochemistry.
Y. Takemoto, T. Ibuka, Y. Takemoto, Y. Baba, N. Yoshikawa, C. Iwata and T. Tanaka, Chem. Commun., 1998, 1911 DOI: 10.1039/A805171B
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