Palladium-catalyzed carbon–carbon bond coupling reactions, the Heck and Stille reactions, proceed in supercritical carbon dioxide with a number of phosphine ligands including tris[3,5-bis(trifluoromethyl)phenyl]phosphine, which affords high conversions and selectivities.
D. K. Morita, S. A. David, W. Tumas, D. K. Morita, D. R. Pesiri and W. H. Glaze, Chem. Commun., 1998, 1397 DOI: 10.1039/A802621A
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