Gentle thermolysis of compound 1, an intermediate in the isomerisation of an overcrowded icosahedral carbametallaborane, surprisingly yields two rearranged products, compound 2 (expected from theory) and compound 3 (unexpected).
S. Dunn and A. S. Weller, Chem. Commun., 1998, 1065 DOI: 10.1039/A709061G
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