A voltammetric method and homogeneous redox catalysis have been used to determine rate constants for the electrode and solution electron transfer to chlorobenzene and its formal potential in four aprotic solvents. It has been shown that both reactions are adiabatic and are controlled by the overdamped solvent relaxation.
J. S. Jaworski and P. Leszczyński, J. Chem. Soc., Faraday Trans., 1997, 93, 3529 DOI: 10.1039/A702711G
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