Issue 22, 1997
From the journal:

Chemical Communications

Novel pyridyl-stabilised rigid-rod organometallic polymers and their monomeric precursors

Christopher J. Adams  and  Stuart L. James  

Abstract

Reaction of trans-[Pt(NC5H4CHBun2)2Cl2] 1 with an excess of HC[triple bond, length half m-dash]CR (R = Ph, C6H4Me, C6H4NO2) affords the monomeric complex trans-[Pt(NC5H4CHBun2)2(C[triple bond, length half m-dash]CR)2] (R = Ph 2a, C6H4Me 2b, C6H4NO2 2c), the trans arrangement of the alkynyl ligands being confirmed from spectroscopic data and by an X-ray analysis of 2c; when 1 is treated with 1 equiv. of HC[triple bond, length half m-dash]CC6H2(Me)2C[triple bond, length half m-dash]CH the polymer [Pt(NC5H4CHBun2)2C[triple bond, length half m-dash]CC6H2Me2C[triple bond, length half m-dash]C]n is formed, which is soluble in a range of organic solvents.

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Article information

DOI
https://doi.org/10.1039/A706586H
Article type
Paper

Chem. Commun., 1997, 2155-2156

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Novel pyridyl-stabilised rigid-rod organometallic polymers and their monomeric precursors

C. J. Adams and S. L. James, Chem. Commun., 1997, 2155 DOI: 10.1039/A706586H

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