Titanium silsesquioxane complexes [Ti(L)(R7Si7O12)], possessing tripodal geometry, represent models for heterogeneous titanosilicate catalysts; the new complexes are exceptionally active and selective catalysts for liquid phase alkene epoxidation reactions.
M. Crocker, R. H. M. Herold, M. Crocker and A. Guy Orpen, Chem. Commun., 1997, 2411 DOI: 10.1039/A704969B
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