Preparation and characterisation of a dithiadiazolyline complex: X-ray crystal structure of [Pd2{µ-SNC(Ph)N(H)S-S,S′}(dppe) 2][BF4]2·3CDCl3
Abstract
While the protonated dithiadiazolyl compound, PhC![[upper bond 1 start]](https://www.rsc.org/images/entities/char_e010.gif)
NSSN![[upper bond 1 end]](https://www.rsc.org/images/entities/char_e011.gif)
H
1 is unknown, oxidation of [Pd(dppe)
2
] with
[PhCNSSN]
2
yields the monometallic complex
[Pd{SNC(Ph)NS-S,S′}(dppe)] 2 which can be
oxidized with [NO][BF
4
] in the presence of moisture to yield
the dimetallic complex
[Pd
2
{µ-SNC(Ph)N(H)S-S,S′}(dppe)
2
][BF
4
]
2
3 which contains coordinated 1;
the X-ray crystal structure of 3 is reported as its solvate
3·3CDCl
3
.
NSSNH
1 is unknown, oxidation of [Pd(dppe)
2
] with
[PhCNSSN]
2
yields the monometallic complex
[Pd{SNC(Ph)NS-S,S′}(dppe)] 2 which can be
oxidized with [NO][BF
4
] in the presence of moisture to yield
the dimetallic complex
[Pd
2
{µ-SNC(Ph)N(H)S-S,S′}(dppe)
2
][BF
4
]
2
3 which contains coordinated 1;
the X-ray crystal structure of 3 is reported as its solvate
3·3CDCl
3
.
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