A stable high-valent oxoferryl porphyrin radical cation is electrochemically generated in aqueous media at room temperature which rapidly catalyses the oxidation of alkenes to give eneones and diols; by contrast the oxoferryl porphyrin only slowly catalyses oxidation and gives only the eneone.
M. Liu, C. Yeh and Y. O. Su, Chem. Commun., 1996, 1437 DOI: 10.1039/CC9960001437
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