Microporous titanosilicates ETS-10 and ETS-4 are synthesized under hydrothermal conditions using solid TiO2 as a source of titanium; the transformation of anatase and rutile phases to the ETS products is found to be direct without involving intermediate amorphous phases.
X. Liu and J. K. Thomas, Chem. Commun., 1996, 1435 DOI: 10.1039/CC9960001435
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