Addition of ButNC to [Ru5(µ5-C2)(µ-SMe)2(µ-PPh2)2(CO)10] 1 results in expansion of the Ru5 polygon and flattening of the C2Ru5 cluster so that in the product 2 one carbon atom acquires a planar tetracoordinate configuration; reversible loss of CO from 2 affords a CNBut derivative of 1.
C. J. Adams, M. I. Bruce, B. W. Skelton and A. H. White, Chem. Commun., 1996, 975 DOI: 10.1039/CC9960000975
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