An Intramolecular Michael–aldol reaction sequence upon 3-acetoacetoxycholest-4-en-6-ones leads stereoselectively to the corresponding 3,6-dihydroxytetrahydrobenzo[4,5,6]cholestan-5′(6′H)-ones.
J. R. Bull and J. H. S. Borry, J. Chem. Soc., Perkin Trans. 1, 1994, 913 DOI: 10.1039/P19940000913
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