Phenyliodonium diacetate (PIDA) in methanol interacts smoothly with phenols to yield p-quinones, o-quinones, 4,4-dialkoxycyclohexa-2,5-dienones or-4-alkyl-4-alkoxycyclohexa-2,5-dienones, dependant on the constitution of the phenolic substrate. The reactions proceed in mild conditions and good yields and are synthetically useful.
A. Pelter and S. M. A. Elgendy, J. Chem. Soc., Perkin Trans. 1, 1993, 1891 DOI: 10.1039/P19930001891
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