Reaction of tetramesityldisilene, 1, with Cyclohexene oxide in benzene at 80 °C gives silyl enol ether, 2, as the major product along with the products of epoxide deoxygenation, Cyclohexene and the known tetramesityldisilaoxirane,3; reaction of 1 with Cyclohexene sulfide occurs rapidly at room temp, to give the known tetramesityldisilathiirane, 6, and Cyclohexene.
J. E. Mangette, D. R. Powell and R. West, J. Chem. Soc., Chem. Commun., 1993, 1348 DOI: 10.1039/C39930001348
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