Photolabilisation of the triphenylphosphine ligand in the aminocarbene complex [(η5-C5H5)Fe(CO)(PPh3)
C(NHCH2Ph)Me]+ BF4–
Abstract
Photolysis of [(η5-C5H5)Fe(CO)(PPh3)
C(NHCH2Ph)Me]+ BF4– and related aminocarbene complexes leads to exclusive loss of the phosphine ligand rather than the carbon monoxide ligand.
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C(NHCH2Ph)Me]+ BF4–