Issue 15, 1992
From the journal:

Journal of the Chemical Society, Chemical Communications

Transition metal enolate chemistry. Formation of a palladium alkyl complex from a highly reactive enolato palladium complex

Fadila Balegroune,   Daniel Grandjean,   Dominique Lakkis  and  Dominique Matt  

Abstract

The ester-derived palladium enolate [LPd{Ph2PCH[double bond, length half m-dash]C(O)OEt}]1(L =o-C6H4CH2NMe2) reacts instantly with dimethyl acetylenedicarboxylate and tetracyanoethylene in tetrahydrofuran (THF) to yield respecitively the alkenyl complex [LPd{Ph2PCH[C(O)OEt](MeO2CC[double bond, length half m-dash]CCO2Me)}]2 and the alkyl complex [LPd{Ph2PCH[C(O)OEt][(NC)2CC(CN2)]}]3.

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Article information

DOI
https://doi.org/10.1039/C39920001084
Article type
Paper

J. Chem. Soc., Chem. Commun., 1992, 1084-1085

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Transition metal enolate chemistry. Formation of a palladium alkyl complex from a highly reactive enolato palladium complex

F. Balegroune, D. Grandjean, D. Lakkis and D. Matt, J. Chem. Soc., Chem. Commun., 1992, 1084 DOI: 10.1039/C39920001084

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