Methyl formate is selectively produced in the dehydrogenation of methanol over Pd/ZnO; the reaction is suggested to proceed through the same steps as over copper-based catalysts.
N. Iwasa, O. Yamamoto, T. Akazawa, S. Ohyama and N. Takezawa, J. Chem. Soc., Chem. Commun., 1991, 1322 DOI: 10.1039/C39910001322
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