Methylation of an α-sulphinyl carbanion, not stabilized by Intramolecular chelation, leads to inversion of configuration, whereas reaction with water or formaldehyde proceeds with retention of configuration.
R. Tanikaga and T. Murashima, J. Chem. Soc., Perkin Trans. 1, 1989, 2142 DOI: 10.1039/P19890002142
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