Cycloaddition of pyridinium ylides to α-chloroacrylonitrile give indolizines: the regioselectivity of the reaction can be rationalized in terms of nucleophilic attack by the ylides on the olefin.
R. Bonneau, M. T. H. Liu and R. Lapouyade, J. Chem. Soc., Perkin Trans. 1, 1989, 1547 DOI: 10.1039/P19890001547
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