Two-electron and four-electron reduction of dioxygen by an acid-stable NADH model compound, 10-methylacridan, occurs efficiently when catalysed by metalloporphyrins and by both metalloporphyrins and iodide ion in the presence of perchloric acid in acetonitrile, respectively.
S. Fukuzumi, S. Mochizuki and T. Tanaka, J. Chem. Soc., Chem. Commun., 1989, 391 DOI: 10.1039/C39890000391
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