Phenyl vinyl sulphone exhibits unusual cathodic behaviour in organic media containing a small excess of a proton donor such as acetic acid or phenol; both the saturated sulphone and an unsaturated dimer are isolated, the formation of which may be explained by hydrogen atom transfer between the organic free radicals formed at the interface.
N. Djeghidjegh and J. Simonet, J. Chem. Soc., Chem. Commun., 1988, 1317 DOI: 10.1039/C39880001317
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