Issue 11, 1988
From the journal:

Journal of the Chemical Society, Chemical Communications

The first example of a direct formal gold(I)–gold(III) bond. Synthesis and structure of [{Au(CH2)2PPh2}2Au(C6F5)3]

Rafael Usón,   Antonio Laguna,   Mariano Laguna,   Maria Teresa Tartón  and  Peter G. Jones  

Abstract

The reaction of [Au(CH2)2PPh2]2 with Au(C6F5)3·OEt2 affords the trinuclear gold complex [{Au(CH2)2PPh2}2Au(C6F5)3]; the AuI–AuIII bond length is 2.572(1)Å.

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Article information

DOI
https://doi.org/10.1039/C39880000740
Article type
Paper

J. Chem. Soc., Chem. Commun., 1988, 740-741

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The first example of a direct formal gold(I)–gold(III) bond. Synthesis and structure of [{Au(CH2)2PPh2}2Au(C6F5)3]

R. Usón, A. Laguna, M. Laguna, M. T. Tartón and P. G. Jones, J. Chem. Soc., Chem. Commun., 1988, 740 DOI: 10.1039/C39880000740

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