Thiophene derivatives can exhibit a novel intramolecular nonbonded S ⋯ N attraction which is observed in 2-formylthiophene semicarbazone, as well as other derivatives.
A. E. Koziol, R. C. Palenik and G. J. Palenik, J. Chem. Soc., Chem. Commun., 1988, 226 DOI: 10.1039/C39880000226
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