Issue 20, 1987
From the journal:

Journal of the Chemical Society, Chemical Communications

Activation of dichloromethane by basic rhodium(I) and iridium(I) phosphine complexes. Synthesis and structures of fac-[Rh(PMe3)3Cl2(CH2PMe3)]Cl·CH2Cl2 and trans-[Rh(Me2PCH2CH2PMe2)2Cl(CH2Cl)]Cl

Todd B. Marder,   William C. Fultz,   Joseph C. Calabrese,   Richard L. Harlow  and  David Milstein  

Abstract

Sixteen-electron RhI complexes of basic phosphines react with CH2Cl2 yielding either RhCH2Cl or RhCH2PMe3 complexes; an example of each has been structurally characterized.

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Article information

DOI
https://doi.org/10.1039/C39870001543
Article type
Paper

J. Chem. Soc., Chem. Commun., 1987, 1543-1545

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Activation of dichloromethane by basic rhodium(I) and iridium(I) phosphine complexes. Synthesis and structures of fac-[Rh(PMe3)3Cl2(CH2PMe3)]Cl·CH2Cl2 and trans-[Rh(Me2PCH2CH2PMe2)2Cl(CH2Cl)]Cl

T. B. Marder, W. C. Fultz, J. C. Calabrese, R. L. Harlow and D. Milstein, J. Chem. Soc., Chem. Commun., 1987, 1543 DOI: 10.1039/C39870001543

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