Non-chelation-controlled Grignard-like and aldol additions to O-silyl protected α-hydroxyketones are possible for the first time using titanium reagents of reduced Lewis-acidity.
M. T. Reetz and M. Hüllmann, J. Chem. Soc., Chem. Commun., 1986, 1600 DOI: 10.1039/C39860001600
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